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71.
Iqbal Saeed Raza Aadil Butt Muhammad Fasih Uddin Mirza Jawad Iqbal Muhammad Ghafoor Salman El-Hajjar Mohammed 《Optical Review》2021,28(3):278-288
Optical Review - In this paper, we propose a full duplex architecture based on a hybrid link composed of free space optics (FSO) and multimode plastic optical fiber (MMPOF) for short-range wireless... 相似文献
72.
Dr. Sunyoung Lee Dr. Sonia Diab Pierre Queval Dr. Muriel Sebban Dr. Isabelle Chataigner Prof. Serge R. Piettre 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(22):7181-7192
Non‐stabilized azomethine ylide 4 a reacts smoothly at room temperature with a variety of uncomplexed aromatic heterocycles and carbocycles on the condition that the ring contains at least one or two electron‐withdrawing substituents, respectively. Aromatic substrates, including pyridine and benzene derivatives, participate as 2 π components in [3+2] cycloaddition reactions and interact with one, two, or three equivalent(s) of the ylide, depending on their structure and substitution pattern. Thus, this process affords highly functionalized polycyclic structures that contain between one and three pyrrolidinyl ring(s) in useful yields. These results indicate that the site selectivity of the cycloaddition reactions strongly depends on both the nature and the positions of the substituents. In most cases, the second 1,3‐dipolar reaction occurs on the opposite face to the one that contains the first pyrrolidinyl ring. DFT calculations on model compounds indicate that a concerted mechanism features a low activation barrier. 相似文献
73.
Roberta Del Sole Anna Scardino Maria Rosaria Lazzoi Lucia Mergola Sonia Scorrano Giuseppe Vasapollo 《Mikrochimica acta》2013,180(15-16):1401-1409
A molecularly imprinted polymer (MIP) for the specific retention of neopterin has been developed. A set of 6 polymers was prepared by radical polymerization under different experimental condition using methacrylic acid as functional monomer and ethylene glycol dimethacrylate as crosslinker, with the aim to understand their influence on the efficiency of the MIP. The performance of each MIP was tested in batch experiments via their binding capacity. The MIP prepared in the presence of nickel ions in dimethylsulfoxide-acetonitrile mixture (P4) exhibited the highest binding capacity for neopterin (260 μmol per gram of polymer). A selectivity study with two other pteridines demonstrated the polymer P4 also to possess the best selectivity. Figure
A molecularly imprinted polymer for the specific retention of neopterin was developed. A set of 6 polymers was prepared under different experimental condition. The performance of each MIP was tested through their binding capacity. The MIP P4 prepared in the presence of nickel ions exhibited the highest binding capacity 相似文献
74.
The reactions of 2,2,2-trichloro-1-phenylethanone with various oxygen, carbon and sulfur nucleophiles were investigated with a view of widening the use of trichloroethanones as acylating agents. 相似文献
75.
Parthasarathy Saravanan Suparna Gupta Arpita DattaGupta Sonia Gupta Vinod K. Singh 《合成通讯》2013,43(15):2695-2699
The cleavage of α-hydroxy tert-butyldimethylsilyl ether to diol takes place efficiently with LAH. It has been proposed that the reaction proceeds via intramolecular hydride transfer from the alkoxy aluminium hydride. In order to substantiate this, reduction of TBDMS ether with LAH in a variety of substrates was studied. 相似文献
76.
Sonia Ben Abdelkhalek Nabil Kallel Sami Kallel Octavio Peña Mohamed Oumezzine 《Journal of magnetism and magnetic materials》2012
Critical behavior in the La0.6Sr0.4Mn0.8Fe0.1Cr0.1O3 ceramics was studied using magnetization methods. Results show that the paramagnetic–ferromagnetic transition is of second order. Based on the critical behavior analysis using the Banerjee criterion and the Kouvel–Fisher method, we find the critical exponents: β=0.395±0.010, γ=1.402±0.010, and δ=5.208±0.007, for which the magnetic interaction is satisfied within the three-dimensional Heisenberg model. Results indicate the presence of short-range interactions. The magnetic entropy change (−ΔSM) reached maximum values of 1.75, 1.45, 1.15, 0.8 and 0.43 J Kg−1 K−1 under a magnetic field variation of 5, 4, 3, 2 and 1 T, respectively. Nevertheless, these (−ΔSM) values are much low for any potential application at this moment. The nature of this phenomenon is discussed in relation to the characteristics of the magnetic phase transition and critical exponents. 相似文献
77.
We are interested in the numerical simulation of wave propagation in media which are a local perturbation of an infinite periodic one. The question of finding artificial boundary conditions to reduce the actual numerical computations to a neighborhood of the perturbation via a DtN operator was already developed in [1] at the continuous level. We deal in this article with the numerical aspects associated to the discretization of the problem. In particular, we describe the construction of discrete DtN operators that relies on the numerical solution of local cell problems, non stationary Ricatti equations and the discretization of non standard integral equations in Floquet variables. 相似文献
78.
Sonia de Almeida Evaneide N. Lima Marisa S. Crespi Clóvis A. Ribeiro Valdir Schalch 《Journal of Thermal Analysis and Calorimetry》2009,97(2):529-533
Urban solid residues are constituted of food remaining, grass leaves, fruit peelings, paper, cardboard, rubber, plastic, etc.
The organic fraction formed represents about 50% during the decomposition yields biogas and leachate, which are sources of
pollution. Residue samples were collected from the landfill in different and cells from several ages and the corresponding
leachate, both after treatments, were submitted to thermal analysis. Kinetic parameters were determined using Flynn–Wall–Ozawa
method. The linear relation between the two kinetic parameters (ln A and E) was verified for organic residue urban’s samples, but not for leachate’s sample. The occurred difference can be attributed
to the constituents present in leachate. 相似文献
79.
Giulio Oliviero Paolo Bergese Marcella Chiari Marina Cretich Sonia Fiorilli Carlo Ricciardi Laura E. Depero 《Analytica chimica acta》2008,630(2):161-167
An innovative route to activate silicon microcantilevers (MCs) for label free molecular recognition is presented. The method consists in coating the underivatized MCs with a functional ter-polymer based on N,N-dimethylacrylamide (DMA) bearing N-acryloyloxysuccinimide (NAS) and 3-(trimethoxysilyl)propyl-methacrylate (MAPS), two functional monomers that confer to the polymer the ability to react with nucleophilic species on biomolecules and with glass silanols, respectively. The polymer was deposited onto MCs by dip coating. Polymer coated MCs were tested in both static and dynamic modes of actuation, featuring detection of DNA hybridization as well as protein/protein interaction. In the dynamic experiments, focused on protein detection, the MCs showed an average mass responsivity of 0.4 Hz/pg for the first resonant mode and of 2.5 Hz/pg for the second resonant mode. The results of the static experiments, dedicated to DNA hybridization detection, allowed for direct estimation of the DNA duplex formation energetics, which resulted fully consistent with the nominal expected values. These results, together with easiness and cheapness, high versatility, and excellent stability of the recognition signal, make the presented route a reliable alternative to standard SAM functionalization (for microcantilevers (MCs) and for micro-electro-mechanical systems (MEMS) in general). 相似文献
80.
Fernando Cruz Moraes Sonia Tomie Tanimoto Giancarlo Richard Salazar‐Banda Sergio Antonio Spinola Machado Lucia Helena Mascaro 《Electroanalysis》2009,21(9):1091-1098
The electrochemical detection of the hazardous pollutant 4‐nitrophenol (4‐NP) at low potentials, in order to avoid matrix interferences, is an important research challenge. This study describes the development, electrochemical characterization and utilization of a multiwall carbon nanotube (MWCNT) film electrode for the quantitative determination of 4‐NP in natural water. Electrochemical impedance spectroscopy measurements showed that the modified surface exhibits a decrease of ca. 13 times in the charge transfer resistance when compared with a bare glassy carbon (GC) surface. Voltammetric experiments showed the possibility to oxidize a hydroxylamine layer (produced by the electrochemical reduction of 4‐NP on the GC/MWNCT surface) in a potential region which is approximately 700 mV less positive than that needed to oxidize 4‐NP, thus minimizing the interference of matrix components. The limit of detection for 4‐NP obtained using square‐wave voltammetry (0.12 μmol L?1) was lower than the value advised by EPA. A natural water sample from a dam located in São Carlos (Brazil) was spiked with 4‐NP and analyzed by the standard addition method using the GC/MWCNT electrode, without any further purification step. The recovery procedure yielded a value of 96.5% for such sample, thus confirming the suitability of the developed method to determine 4‐NP in natural water samples. The electrochemical determination was compared with that obtained by HPLC with UV‐vis detection. 相似文献